We have studied reviewer’s comments carefully and have made revision which marked in red in the paper. The manuscript PAT-09-234 has been carefully revised and some new data were added in the revised text (please see Table 2), and the major revisions were marked in red. Answer: We accept the referee’s suggestion, the units for wavenumber have been labelled in the plot, please see the X-axis in Figure 1 in the revised manuscript. The explain was given in question 2, please see the answer to question 2 and the lines 5-14 on page 13 in the revised text. Answer: This comment was highly appreciated. Due to these reasons, the thermal stability of the prepared membranes was highlighted and the mechanical stability of the membrane was not reported in this manuscript. Consequently, we think it is not necessary to highlight membrane conductivity of the prepared negatively charged hybrid membranes and these data were not reported in this manuscript. Answer: These errors have been corrected and the related paragraph has been rewritten in the revised manuscript. For their applications in industry especially in environmental field, further work is thus required to optimize the membrane preparation process so as to highly elevate the IEC values of these hybrid membranes.

” should be “50oC”.

suggestions In our case, the prepared membranes expect to be used in environmental field, not be used to separate species by pressure, thus we mainly concern their thermal stability rather than their mechanical strength. This is because in this case we mainly concern the ion-exchange capacity rather than the proton conductivity. Q3. In Fig 2, the units for wavenumber should be shown in the diagram. Q4. Author should also include proposed applications for the reported membranes. ” should be “50oC”.   “人之初,性本善”。 ”. Fig 4 indicated that the gel time of 30%HBPSIEP/BCE at 160 oC is about 100min. if the resin has been cured in degassing process? Answer: We accept the referee’s suggestion, this error has been corrected in the revised manuscript. This would have been attractive feature of the manuscript. Nonetheless, for hybrid membranes potentially used in non-pressure operating condition, thermal stability may be more attractive in that they expects to be used in higher temperature and strongly oxidizing circumstances for industrial applications (as stated in the abstract). Q1. Authors reported negatively charged membrane but they did not studied membrane conductivity, which is essential property to asses, the suitability of charged membrane. Answer: As the referee’s comment pointed out, membrane conductivity is really the essential property to evaluate the suitability of charged membrane, especially for their applications in fuel cells.

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Answer: As the referee’s comment pointed out, the ion-exchange capacities (IECs) of the prepared membranes were relatively lower. Answer: As the referee’s comment pointed out, good mechanical stability of a membrane can conduce to its application especially for its use in industrial separation by pressure. Consequently, hybridization technique is used to increase the membrane’s mechanical and stability. But author failed to include any information on the mechanical stability of the membrane. Geneally speaking, organic membrane has lower mechanical strength and stability, it can not meet the need of separation in industry. We appreciate the detailed and useful comments and suggestions from you and referees. Except selling products,we pay attention to after-sales service also.we will provide best plan and suggestions on application method ,dosage and so on according your local situation. As the referee’s comment suggested,when the membrane properties are greatly improved, their applications in industry will be further investigated. We believe this problem will be solved with the further improvement on membrane properties and optimization of operational parameters. The main purpose of this manuscript is to develop new preparation technique of negatively charged hybrid membranes.在柳如梦的游说下,终于同意了跟柳如梦一起在酒店坐台(卖艺不卖身)。

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